Weak Acid pH Formula:
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The weak acid pH formula estimates the pH of a weak acid solution based on its acid dissociation constant (pKa) and concentration. This approximation is valid for weak acids that only partially dissociate in aqueous solution.
The calculator uses the weak acid pH formula:
Where:
Explanation: This formula provides an approximate pH calculation for weak acids, assuming the acid dissociation is small and the contribution from water autoionization is negligible.
Details: Accurate pH calculation for weak acids is essential in chemical analysis, pharmaceutical formulations, biological systems, and industrial processes where pH control is critical.
Tips: Enter pKa value (unitless) and concentration in molarity (M). Both values must be positive numbers. The calculator provides an approximate pH value for weak acid solutions.
Q1: What is the range of validity for this formula?
A: This approximation works best for weak acids with pKa values between 2 and 12 and concentrations between 0.001 M and 0.1 M.
Q2: Why is this an approximation?
A: This formula assumes [H+] from water autoionization is negligible and that the acid dissociation is small compared to the initial concentration.
Q3: When should I use the exact calculation instead?
A: Use exact calculations for very dilute solutions, very strong or very weak acids, or when high precision is required.
Q4: What are typical pKa values for common weak acids?
A: Acetic acid: 4.76, Formic acid: 3.75, Carbonic acid: 6.35, Hydrocyanic acid: 9.21.
Q5: How does temperature affect the calculation?
A: Temperature affects both pKa values and the ionic product of water, so for precise work, use temperature-corrected values.